1-Hexyl-3-methylimidazolium Hexafluorophosphate

Catalog Number

ACM304680351-1

CAS

304680-35-1

Structure

Description

1-Hexyl-3-methylimidazolium hexafluorophosphate is a water-immiscible imidazolium-type room temperature ionic liquid, suitable for electrochemistry. It can be used as a chelate extraction solvent for divalent metal cations using 4,4,4-trifluoro-1-(2-thienyl)-1,3-butanedione (thenoyltrifluoroacetone, Htta) as an extractant.

Synonyms

HMIMPF6

IUPAC Name

1-hexyl-3-methylimidazol-3-ium;hexafluorophosphate

Molecular Weight

312.24

Molecular Formula

C10H19F6N2P

Canonical SMILES

CCCCCCN1C=C[N+](=C1)C.F[P-](F)(F)(F)(F)F

InChI

1S/C10H19N2.F6P/c1-3-4-5-6-7-12-9-8-11(2)10-12;1-7(2,3,4,5)6/h8-10H,3-7H2,1-2H3;/q+1;-1

InChI Key

YPWSSSRXUOQNMQ-UHFFFAOYSA-N

Boiling Point

>350 °C (lit.)

Melting Point

25-35 °C

Flash Point

Not applicable

Purity

>98.0%(T)(N)

Density

1.30 g/cm³ (23 °C)

Appearance

Colorless to Light orange to Yellow clear liquid

Application

Metal Plating, Electropolishing, Metal Reprocessing, Phase transfer media, Batteries Fuel Cells, Nanomaterials, Industrial Solvents, Nuclear Fuel Red Waste, Enzymatic Catalysis, Lubricants Heat Transfer and Solar Energy Conversion.

Storage

Store under inert gas, 2-8°C

Chemical Formula

HMIMPF6

Complexity

177

Conductivity

0.80 mS/cm (30 °C)

Covalently-Bonded Unit Count

2

Electrochemical Window

5.5 V

Empirical Formula

C10H19F6N2P

Exact Mass

312.119005g/mol

Hazard Statements

H315 : Causes skin irritation.H319 : Causes serious eye irritation.

Heavy Atom Count

19

HSN Code

29332990

MDL Number

MFCD03093296

Monoisotopic Mass

312.119005g/mol

Precautionary Statements

P264 : Wash skin thoroughly after handling.P280 : Wear protective gloves/ eye protection/ face protection.P337 + P313 : If eye irritation persists: Get medical advice/ attention.P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.P302 + P352 : IF ON SKIN: Wash with plenty of soap and water.P332 + P313 : If skin irritation occurs: Get medical advice/ attention.P362 : Take off contaminated clothing and wash before reuse.

REAXYS Number

8955409

Refractive Index

n20/D 1.419

Viscosity

465 cP (25 °C)

• Catalog Number: ACM304680351-1
• CAS: 304680-35-1
• Description: 1-Hexyl-3-methylimidazolium hexafluorophosphate is a water-immiscible imidazolium-type room temperature ionic liquid, suitable for electrochemistry. It can be used as a chelate extraction solvent for divalent metal cations using 4,4,4-trifluoro-1-(2-thienyl)-1,3-butanedione (thenoyltrifluoroacetone, Htta) as an extractant.
• Synonyms: HMIMPF6
• IUPAC Name: 1-hexyl-3-methylimidazol-3-ium;hexafluorophosphate
• Molecular Weight: 312.24
• Molecular Formula: C10H19F6N2P
• Canonical SMILES: CCCCCCN1C=C[N+](=C1)C.F[P-](F)(F)(F)(F)F
• InChI: 1S/C10H19N2.F6P/c1-3-4-5-6-7-12-9-8-11(2)10-12;1-7(2,3,4,5)6/h8-10H,3-7H2,1-2H3;/q+1;-1
• InChI Key: YPWSSSRXUOQNMQ-UHFFFAOYSA-N
• Boiling Point: >350 °C (lit.)
• Melting Point: 25-35 °C
• Flash Point: Not applicable
• Purity: >98.0%(T)(N)
• Density: 1.30 g/cm³ (23 °C)
• Appearance: Colorless to Light orange to Yellow clear liquid
• Application: Metal Plating, Electropolishing, Metal Reprocessing, Phase transfer media, Batteries Fuel Cells, Nanomaterials, Industrial Solvents, Nuclear Fuel Red Waste, Enzymatic Catalysis, Lubricants Heat Transfer and Solar Energy Conversion.
• Storage: Store under inert gas, 2-8°C
• Chemical Formula: HMIMPF6
• Complexity: 177
• Conductivity: 0.80 mS/cm (30 °C)
• Covalently-Bonded Unit Count: 2
• Electrochemical Window: 5.5 V
• Empirical Formula: C10H19F6N2P
• Exact Mass: 312.119005g/mol
• Hazard Statements: H315 : Causes skin irritation.H319 : Causes serious eye irritation.
• Heavy Atom Count: 19
• HSN Code: 29332990
• MDL Number: MFCD03093296
• Monoisotopic Mass: 312.119005g/mol
• Precautionary Statements: P264 : Wash skin thoroughly after handling.P280 : Wear protective gloves/ eye protection/ face protection.P337 + P313 : If eye irritation persists: Get medical advice/ attention.P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.P302 + P352 : IF ON SKIN: Wash with plenty of soap and water.P332 + P313 : If skin irritation occurs: Get medical advice/ attention.P362 : Take off contaminated clothing and wash before reuse.
• REAXYS Number: 8955409
• Refractive Index: n20/D 1.419
• Viscosity: 465 cP (25 °C)