1-Butyl-3-methylimidazolium Hydrogen Sulfate

Catalog Number

ACM262297132

CAS

262297-13-2

Structure

Description

1-Butyl-3-methylimidazolium hydrogen sulfate is an acidic ionic liquid. [BMIM][HSO4] can be used as an additive to accelerate current efficiency, lower power consumption, and enhance the surface morphology during the electrodeposition of zinc from acidic sulfate solutions. The combination of sodium nitrate and [BMIM][HSO4] can be used as a nitrating agent for the selective nitration of phenols to afford its corresponding nitro derivatives.

Synonyms

BMIMHSO4

IUPAC Name

1-butyl-3-methylimidazol-3-ium;hydrogen sulfate

Molecular Weight

236.29

Molecular Formula

C8H16N2O4S

Canonical SMILES

CCCCN1C=C[N+](=C1)C.OS(=O)(=O)[O-]

InChI

1S/C8H15N2.H2O4S/c1-3-4-5-10-7-6-9(2)8-10;1-5(2,3)4/h6-8H,3-5H2,1-2H3;(H2,1,2,3,4)/q+1;/p-1

InChI Key

KXCVJPJCRAEILX-UHFFFAOYSA-M

Melting Point

~70 °C

Flash Point

543.2 °F

Purity

>97.0%(HPLC)(N)

Solubility

soluble in Methanol

Appearance

Colorless to Red to Green clear liquid

Application

Metal Plating, Electropolishing, Metal Reprocessing, Phase transfer media, Batteries Fuel Cells, Nanomaterials, Industrial Solvents, Nuclear Fuel Red Waste, Enzymatic Catalysis, Lubricants Heat Transfer and Solar Energy Conversion.

Storage

Store under inert gas, -20℃

Chemical Formula

BMIMHSO4

Complexity

169

Covalently-Bonded Unit Count

2

Exact Mass

236.08307817g/mol

Hazard Statements

H314 : Causes severe skin burns and eye damage.H290 : May be corrosive to metals.

Heavy Atom Count

15

MDL Number

MFCD06798197

Monoisotopic Mass

236.08307817g/mol

Precautionary Statements

P501 : Dispose of contents/ container to an approved waste disposal plant.P234 : Keep only in original container.P264 : Wash skin thoroughly after handling.P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.P390 : Absorb spillage to prevent material damage.P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.P363 : Wash contaminated clothing before reuse.P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.P406 : Store in corrosive resistant container with a resistant inner liner.P405 : Store locked up.

REAXYS Number

10035901

Refractive Index

n20/D 1.41

Topological Polar Surface Area

94.6Ų

• Catalog Number: ACM262297132
• CAS: 262297-13-2
• Description: 1-Butyl-3-methylimidazolium hydrogen sulfate is an acidic ionic liquid. [BMIM][HSO4] can be used as an additive to accelerate current efficiency, lower power consumption, and enhance the surface morphology during the electrodeposition of zinc from acidic sulfate solutions. The combination of sodium nitrate and [BMIM][HSO4] can be used as a nitrating agent for the selective nitration of phenols to afford its corresponding nitro derivatives.
• Synonyms: BMIMHSO4
• IUPAC Name: 1-butyl-3-methylimidazol-3-ium;hydrogen sulfate
• Molecular Weight: 236.29
• Molecular Formula: C8H16N2O4S
• Canonical SMILES: CCCCN1C=C[N+](=C1)C.OS(=O)(=O)[O-]
• InChI: 1S/C8H15N2.H2O4S/c1-3-4-5-10-7-6-9(2)8-10;1-5(2,3)4/h6-8H,3-5H2,1-2H3;(H2,1,2,3,4)/q+1;/p-1
• InChI Key: KXCVJPJCRAEILX-UHFFFAOYSA-M
• Melting Point: ~70 °C
• Flash Point: 543.2 °F
• Purity: >97.0%(HPLC)(N)
• Solubility: soluble in Methanol
• Appearance: Colorless to Red to Green clear liquid
• Application: Metal Plating, Electropolishing, Metal Reprocessing, Phase transfer media, Batteries Fuel Cells, Nanomaterials, Industrial Solvents, Nuclear Fuel Red Waste, Enzymatic Catalysis, Lubricants Heat Transfer and Solar Energy Conversion.
• Storage: Store under inert gas, -20℃
• Chemical Formula: BMIMHSO4
• Complexity: 169
• Covalently-Bonded Unit Count: 2
• Exact Mass: 236.08307817g/mol
• Hazard Statements: H314 : Causes severe skin burns and eye damage.H290 : May be corrosive to metals.
• Heavy Atom Count: 15
• MDL Number: MFCD06798197
• Monoisotopic Mass: 236.08307817g/mol
• Precautionary Statements: P501 : Dispose of contents/ container to an approved waste disposal plant.P234 : Keep only in original container.P264 : Wash skin thoroughly after handling.P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.P390 : Absorb spillage to prevent material damage.P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.P363 : Wash contaminated clothing before reuse.P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.P406 : Store in corrosive resistant container with a resistant inner liner.P405 : Store locked up.
• REAXYS Number: 10035901
• Refractive Index: n20/D 1.41
• Topological Polar Surface Area: 94.6Ų