1-Butyl-3-methylimidazolium hexafluorophosphate

Catalog Number

ACM174501645

CAS

174501-64-5

Structure

Description

1-Butyl-3-methylimidazolium hexafluorophosphate is an imidazolium-based, hydrophobic, room temperature ionic liquid (RTIL). It is an ionic liquid employed in many environmentally friendly reactions.

Synonyms

BMIMPF6

IUPAC Name

1-butyl-3-methylimidazol-3-ium;hexafluorophosphate

Molecular Weight

284.19

Molecular Formula

C8H15F6N2P

Canonical SMILES

CCCCN1C=C[N+](=C1)C.F[P-](F)(F)(F)(F)F

InChI

1S/C8H15N2.F6P/c1-3-4-5-10-7-6-9(2)8-10;1-7(2,3,4,5)6/h6-8H,3-5H2,1-2H3;/q+1;-1

InChI Key

IXQYBUDWDLYNMA-UHFFFAOYSA-N

Melting Point

~70 °C

Flash Point

Not applicable

Purity

>98.0%(HPLC)(N)

Density

1.37 g/cm³

Solubility

insoluble in Toluene

Appearance

liquid

Application

1-Butyl-3-methylimidazolium hexafluorophosphate is an ionic liquid

Storage

Store under inert gas, -20℃

Chemical Formula

[BMIM]PF6

Complexity

156

Conductivity

1.92 mS/cm

Covalently-Bonded Unit Count

2

ECW

4.2 V

Empirical Formula

C8H15F6N2P

Exact Mass

284.087704g/mol

Hazard Statements

H315 : Causes skin irritation.H319 : Causes serious eye irritation.

Heavy Atom Count

17

HSN Code

293399

MDL Number

MFCD03093295

Monoisotopic Mass

284.087704g/mol

Precautionary Statements

P264 : Wash skin thoroughly after handling.P280 : Wear protective gloves/ eye protection/ face protection.P337 + P313 : If eye irritation persists: Get medical advice/ attention.P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.P302 + P352 : IF ON SKIN: Wash with plenty of soap and water.P332 + P313 : If skin irritation occurs: Get medical advice/ attention.P362 : Take off contaminated clothing and wash before reuse.

REAXYS Number

8026031

References

Gubicza, L. et al.: Green Chem., 5, 236 (2003); Lozano, P. et al.: J. Mol. Catal. B Enzym., 21, 9 (2003);

Refractive Index

n20/D 1.41

Viscosity

267 cP

• Catalog Number: ACM174501645
• CAS: 174501-64-5
• Description: 1-Butyl-3-methylimidazolium hexafluorophosphate is an imidazolium-based, hydrophobic, room temperature ionic liquid (RTIL). It is an ionic liquid employed in many environmentally friendly reactions.
• Synonyms: BMIMPF6
• IUPAC Name: 1-butyl-3-methylimidazol-3-ium;hexafluorophosphate
• Molecular Weight: 284.19
• Molecular Formula: C8H15F6N2P
• Canonical SMILES: CCCCN1C=C[N+](=C1)C.F[P-](F)(F)(F)(F)F
• InChI: 1S/C8H15N2.F6P/c1-3-4-5-10-7-6-9(2)8-10;1-7(2,3,4,5)6/h6-8H,3-5H2,1-2H3;/q+1;-1
• InChI Key: IXQYBUDWDLYNMA-UHFFFAOYSA-N
• Melting Point: ~70 °C
• Flash Point: Not applicable
• Purity: >98.0%(HPLC)(N)
• Density: 1.37 g/cm³
• Solubility: insoluble in Toluene
• Appearance: liquid
• Application: 1-Butyl-3-methylimidazolium hexafluorophosphate is an ionic liquid
• Storage: Store under inert gas, -20℃
• Chemical Formula: [BMIM]PF6
• Complexity: 156
• Conductivity: 1.92 mS/cm
• Covalently-Bonded Unit Count: 2
• ECW: 4.2 V
• Empirical Formula: C8H15F6N2P
• Exact Mass: 284.087704g/mol
• Hazard Statements: H315 : Causes skin irritation.H319 : Causes serious eye irritation.
• Heavy Atom Count: 17
• HSN Code: 293399
• MDL Number: MFCD03093295
• Monoisotopic Mass: 284.087704g/mol
• Precautionary Statements: P264 : Wash skin thoroughly after handling.P280 : Wear protective gloves/ eye protection/ face protection.P337 + P313 : If eye irritation persists: Get medical advice/ attention.P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.P302 + P352 : IF ON SKIN: Wash with plenty of soap and water.P332 + P313 : If skin irritation occurs: Get medical advice/ attention.P362 : Take off contaminated clothing and wash before reuse.
• REAXYS Number: 8026031
• References: Gubicza, L. et al.: Green Chem., 5, 236 (2003); Lozano, P. et al.: J. Mol. Catal. B Enzym., 21, 9 (2003)
• Refractive Index: n20/D 1.41
• Viscosity: 267 cP